You can easily override theme by wrapping your view into a new Theme instance with custom properties.
You could do the following :
return new MaterialApp(
  // default theme here
  theme: new ThemeData(),
  builder: (context, child) {
    final defaultTheme = Theme.of(context);
    if (defaultTheme.platform == TargetPlatform.iOS) {
      return new Theme(
        data: defaultTheme.copyWith(
          primaryColor: Colors.purple
        ),
        child: child,
      );
    }
    return child;
  }
);
Which would specify a default theme. And then override primaryColor for IOS.