Tolerations do not guarantee that a pod will be scheduled an a node with that taint. It just means that it can tolerate such taints and schedule on those nodes. If you specifically want to deploy your pod on a specific node, use labels. Example, give your master node a label say dedicated=master and set nodeSelector for your pod to look for this label.
to add the label to you node:
kubectl label nodes name_of_your_node dedicated=master
Kubernetes 1.6 and above syntax
nodeSelector for your pod:
apiVersion: apps/v1beta1
kind: Deployment
metadata:
  name: nginx-ingress-controller
  namespace: kube-system
  labels:
    kubernetes.io/cluster-service: "true"
spec:
  replicas: 3
  template:
    metadata:
      labels:
        k8s-app: nginx-ingress-lb
        name: nginx-ingress-lb
      annotations:
    spec:
      nodeSelector:
        dedicated: master
      tolerations:
      - key: dedicated
        operator: Equal
        value: master
        effect: NoSchedule
    […]
You can also use affinity under spec:
affinity:
  nodeAffinity:
    requiredDuringSchedulingIgnoredDuringExecution:
      nodeSelectorTerms:
        matchExpressions:
        - key: dedicated
          operator: Equal
          values: ["master"]
Pre 1.6 syntax
nodeSelector for your pod:
apiVersion: extensions/v1beta1
kind: Deployment
metadata:
  name: nginx-ingress-controller
  namespace: kube-system
  labels:
    kubernetes.io/cluster-service: "true"
spec:
  replicas: 3
  template:
    metadata:
      labels:
        k8s-app: nginx-ingress-lb
        name: nginx-ingress-lb
      annotations:
        scheduler.alpha.kubernetes.io/tolerations: |
          [
            {
              "key": "dedicated",
              "operator": "Equal",
              "value": "master",
              "effect": "NoSchedule"
            }
          ]
    spec:
      nodeSelector:
        dedicated: master
    […]
Annotations instead of nodeSelector:
scheduler.alpha.kubernetes.io/affinity: >
  {
    "nodeAffinity": {
      "requiredDuringSchedulingIgnoredDuringExecution": {
        "nodeSelectorTerms": [
          {
            "matchExpressions": [
              {
                "key": "dedicated",
                "operator": "Equal",
                "values": ["master"]
              }
            ]
          }
        ]
      }
    }
  }
NoSchedule does not stop already scheduled pods. Check https://kubernetes.io/docs/user-guide/node-selection/ for more info.