Hi,
You can use at() method to update your dataset. I have attached one example for your reference.
import pandas as pd
df1=pd.read_csv('my.csv')
| Place | 
State | 
| 0 | 
Kolkata | 
WestBengal | 
| 1 | 
Delhi | 
Delhi | 
| 2 | 
Bangalore | 
Karnataka | 
| 3 | 
Kolkata | 
WestBengal | 
| 4 | 
Delhi | 
Delhi | 
df1.at[0,'Place']= 'Mumbai'
| Place | 
State | 
| 0 | 
Mumbai | 
WestBengal | 
| 1 | 
Delhi | 
Delhi | 
| 2 | 
Bangalore | 
Karnataka | 
| 3 | 
Kolkata | 
WestBengal | 
| 4 | 
Delhi | 
Delhi | 
 
I hope this will help you.